CATENA-POLY[[[BIS(4-METHYLBENZOATO-κ2O,O′)ZINC(II)]-μ-4,4′-BIPYRIDINE-κ2N:N′] TETRAHYDRATE]

catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate]

catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate]

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The asymmetric unit of the title compound, {[Zn(C7H7O2)2(C10H8N2)]·4H2O}n, contains a highly distorted octahedral ZnII metal center strongly coordinated by two N Accessories atoms of two 4,4′-bipyridine (4,4′-bipy) ligands and chelated by two 4-methylbenzoate anions.The crystallographic inversion center and glide plane present at the center of the C—C single bond of 4,4′-bipy, along with the cis coordination motif of the 4,4′-bipy, lead to one-dimensional zigzag chains.There are South Park a large number of water molecules in the crystal structure, which also form one-dimensional chains through O—H.

O hydrogen bonds.

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